Dimerization of cyclopentadiene from side stream from debutanizer

ABSTRACT

A system and a process for dimerizing cyclopentadiene (CPD) including producing a C 6 +C 7  rich bottoms stream and a C 5  rich side draw from a debutanizer, where the C 5  rich side draw and at least a portion of the C 6 +C 7  rich bottoms stream are directed to a dimerizer where the CPD is thermally dimerized to dicyclopentadiene (DCPD). DCPD is more stable than CPD and thus safer to handle.

CROSS REFERENCE TO RELATED APPLICATION

This application claims priority to U.S. Provisional Patent Application having Ser. No. 63/180,282 filed on Apr. 27, 2021 which is incorporated by reference herein.

TECHNICAL FIELD

The present invention relates to a system and a process for indigenously dimerizing cyclopentadiene (CPD), and more particularly relates to dimerizing CPD to give dicyclopentadiene (DCPD) in an ethylene plant.

BACKGROUND

Steam cracking, also referred to as pyrolysis, is the principal process used to produce lighter alkenes (e.g. ethylene), commonly known as olefins, from a naphtha, liquefied petroleum gas (LPG), ethane, propane, and/or butane feedstock.

In a conventional steam cracking process, a gaseous or liquid hydrocarbon feed like naphtha, LPG, or ethane is diluted with steam and briefly heated in a furnace without the presence of oxygen. The cracked gas products produced in the reaction depend on the composition of the feed, the hydrocarbon-to-steam ratio, and on the cracking temperature and furnace residence time. Light hydrocarbon feeds, such as ethane, LPGs, or light naphtha, give cracked gas streams rich in the lighter alkenes, including ethylene, propylene, and butadiene. Heavier hydrocarbons (full range and heavy naphthas as well as other refinery products) additionally yield products rich in aromatic hydrocarbons and hydrocarbons suitable for inclusion in gasoline or fuel oil, such as a C₅₊pyrolysis gasoline stream leaving the bottom of a debutanizer tower used in the olefin plant for separating heavier hydrocarbons in the cracked gas stream from C₄ hydrocarbons. This pyrolysis gasoline stream usually contains C₅ diolefins, mainly cyclopentadienes, that may then be dimerized to make more stable dicyclopentadienes.

Normally in a steam cracking process, where required, a dimerizer is installed on the bottom stream of debutanizer where C₅ diolefins—mainly cyclopentadienes—are dimerized to make more stable dicyclopentadienes. This could be done either to make adhesives and other products from the dicyclopentadienes or simply to transport and store safely the C₅-containing pyrolysis gasoline product.

U.S. Pat. No. 6,258,989 B1 discloses dimerizing a stream comprising C₅ olefins, C₅ diolefins, CPD, DCPD, and aromatics mixture of benzene, toluene, xylene (BTX) and then separating C₅, C₆-C₉ and C₁₀₊for upgrading the molecules. This dimerization is done on a debutanized pyrolysis gasoline stream from a steam cracker. More specifically, U.S. Pat. No. 6,258,989 discloses that a hydrocarbon feedstock containing C₅ olefins, C5 diolefins, CPD, DCPD, and aromatics is processed by the steps of heating a hydrocarbon feedstock containing CPD, DCPD, C₅ diolefins, benzene, toluene, and xylene in a heating zone, to dimerize CPD to DCPD, thereby forming a first effluent; separating the first effluent into a C₆₊ stream and a C₅ diolefin stream; separating the C₆₊ stream into a C₆-C₉ stream and a C₁₀₊ stream; separating the C₁₀₊ stream into a fuel oil stream and a DCPD stream; and hydrotreating the C₆-C₉ stream to thereby form a BTX stream. In an alternate embodiment, the hydrocarbon feedstock is processed by the steps of heating the hydrocarbon feedstock in a heating zone, to dimerize CPD to DCPD, thereby forming a first effluent; separating the first effluent into a C₅-C₉ stream and a C₁₀₊ stream; separating the C₁₀₊ stream into a fuel oil stream and a DCPD stream; contacting the C₅-C₉ stream with a selective hydrogenation catalyst, in a first reaction zone and in the presence of hydrogen, to hydrogenate at least a portion of the diolefins, alkynes, and styrene contained in the C₅-C₉ stream, thereby forming a second effluent; separating the second effluent into a C₆-C₉ stream and a C₅ olefin stream; and contacting the C₆-C₉ stream with a hydrodesulfurization catalyst, in a second reaction zone and in the presence of hydrogen, to desulfurize at least a portion of the sulfur-containing compounds contained in the C₆-C₉ stream thereby forming a BTX stream.

In a related process and system, a debutanizer and a dimerizer produce a C₆-C₇-rich, C₅-free stream that used for making up a solvent for a tar solvation quench system. This provides a unique opportunity for processing CPD.

SUMMARY

There is provided, in one non-limiting embodiment, a system for dimerizing cyclopentadiene (CPD), where the system includes a debutanizer that in turn includes a feed of C₄-C₇ hydrocarbons, a C₄ overhead stream, a C₆+C₇ rich bottoms stream, and a C₅ rich side draw, which system also includes a dimerizer that in turn includes a feed from the C₅ rich side draw, a feed from at least a portion of the C₆+C₇ rich bottoms stream, and a pyrolysis gasoline bottoms product stream.

There is also provided, in a different, non-restrictive version, a process for dimerizing cyclopentadiene (CPD), where the process includes introducing a C₃-C₇ hydrocarbons stream to a debutanizer, debutanizing the C₃-C₇ hydrocarbons thereby producing a C₃+C₄ overhead stream, a C₆+C₇ rich bottoms stream, and a C₅ rich side draw, where the process further includes introducing the C₅ rich side draw and at least a portion of the C₆+C₇ rich bottoms stream to a dimerizer, dimerizing the CPD in the dimerizer, and producing a bottoms product stream.

In another non-limiting embodiment there is provided an ethylene plant that includes a system for dimerizing cyclopentadiene (CPD) as described above.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic illustration a process for dimerizing cyclopentadiene (CPD), and more particularly relates to dimerizing CPD to give dicyclopentadiene (DCPD) in an ethylene plant

DETAILED DESCRIPTION

The hydrocarbon feed 58 to debutanizer column 48 is may include C₃ or C₄ to C₇ hydrocarbons. Since streams C₆-C₇ rich bottoms stream 46, C₅-rich side draw stream 50, and overhead stream 62 contain C₃-C₇ hydrocarbons collectively, hydrocarbon feed 58 should contain C₄-C₇ hydrocarbons and may also contain C₃.

Referring again to the non-limiting embodiment of the cyclopentadiene (CPD) dimerization system 60 and process shown in FIG. 1, the debutanizer column 48 is configured to produce a C₅-rich side draw stream 50. The operating conditions of the debutanizer column 48 include an overhead pressure of from about 29 psia (200 kPa) independently to about 130 psia (896 kPa) depending on condensing media (i.e., refrigerant, cooling water); and an overhead operating temperature ranging from about 1° F.(−17° C.) independently to about 113° F. (45° C.); and a bottoms temperature from about 180° F. (82° C.) independently to about 280° F. (138° C.).

It will be appreciated that the location of C₅-rich side draw stream 50 should be carefully evaluated through simulation of the debutanizer column 48 to ensure that the C₅-rich side draw stream 50 has the highest concentration of C₅ range hydrocarbons in order to minimize the amount of C₅ range hydrocarbons concentration in C₆-C₇ rich bottoms stream 46 of debutanizer column 48. In accordance with this non-limiting embodiment, the C₆-C₇ rich bottoms stream 46 of debutanizer column 48 mainly consists of C₆+C₇ range hydrocarbons.

After drawing any necessary makeup for the optional C₆-C₇ rich tar solvent makeup stream 44, the net debutanizer bottoms stream 52 may be mixed with the C₅-rich side draw stream 50 as feed to a thermal dimerizer 54. The thermal dimerizer 54 may be utilized to dimerize the cyclopentadienes present in the C₅-rich side draw stream 50 and any present in the portion of the C₆-C₇ rich bottoms stream 46 directed to the net debutanizer bottoms stream 52 to dimerize CPD to dicyclopentadiene. This configuration may help to ensure that the combined dimerized pyrolysis gasoline 56 is stabilized to prevent safety hazards in transportation and storage. Any C₆-C₇ molecules from aromatic rich bottoms stream 46 not used or any surplus molecules are blended with dimerized pyrolysis gasoline 56.

In one non-limiting embodiment, the dimerizer 54 is a thermal dimerizer. The operating conditions of the thermal dimerizer 54 include a pressure of from about 35 psia (241 kPa) independently to about 60 psia (414 kPa); alternatively from about 40 psia (276 kPa) independently to about 50 psia (345 kPa); and an operating temperature ranging from about 200° F. (93° C.) independently to about 250° F. (121° C.); alternatively from about 210° F. (99° C.) independently to about 220° F. (104° C.).

The dimerized pyrolysis gasoline 56 may be further processed to make adhesion products, resins, inks, paints, and the like. Optionally, a C₈-C₁₀ steam cracked naphtha (SCN) stream 40 may be combined with dimerized pyrolysis gasoline 56.

In the foregoing specification, the invention has been described with reference to specific embodiments thereof. However, the specification is to be regarded in an illustrative rather than a restrictive sense. For example, debutanizer conditions and configuration, dimerizer conditions and configuration, and the composition and amount of the various hydrocarbon streams falling within the claimed or disclosed parameters, but not specifically identified or tried in a particular example, are expected to be within the scope of this invention.

The present invention may be practiced in the absence of an element not disclosed. In addition, the present invention may suitably comprise, consist or consist essentially of the elements disclosed. For instance, in one non-limiting embodiment there may be provided

There may be additionally provided, in another non-restrictive version, a process for dimerizing cyclopentadiene (CPD), where the process comprises, consists essentially of, or consists of introducing a C₄-C₇ hydrocarbons stream to a debutanizer, debutanizing the C₄-C₇ hydrocarbons thereby producing a C₄ overhead stream, a C₆-C₇ rich bottoms stream, and a C₅ rich side draw, where the process further comprises, consists essentially of, or consists of introducing the C₅ rich side draw and at least a portion of the C₆+C₇ rich bottoms stream to a dimerizer, dimerizing the CPD in the dimerizer, and producing a bottoms product stream.

There may also be provided an ethylene plant comprising a system for dimerizing cyclopentadiene (CPD), where the system comprises, consists essentially of, or consists of a debutanizer that in turn comprises, consists essentially of, or consists of a feed of C₄-C₇ hydrocarbons, a C₄ overhead stream, a C₆+C₇ rich bottoms stream, and a C₅ rich side draw, where the system additionally comprises, consists essentially of, or consists of a dimerizer that in turn comprises, consists essentially of, or consists of a feed from the C₅ rich side draw, a feed from at least a portion of the C₆+C₇ rich bottoms stream, and a pyrolysis gasoline bottoms product stream.

The words “comprising” and “comprises” as used throughout the claims, are to be interpreted to mean “including but not limited to” and “includes but not limited to”, respectively.

To the extent used herein, the word “substantially” shall mean “being largely but not wholly that which is specified.”

As used herein, the singular forms “a,” “an,” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise.

To the extent used herein, the term “about” in reference to a given parameter is inclusive of the stated value and has the meaning dictated by the context (e.g., it includes the degree of error associated with measurement of the given parameter).

As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items. 

What is claimed is:
 1. A system for dimerizing cyclopentadiene (CPD), the system comprising: a debutanizer comprising: a feed of C₄-C₇ hydrocarbons; a C₄ overhead stream; a C₆+C₇ rich bottoms stream; and a C₅ rich side draw; a dimerizer comprising: a feed from the C₅ rich side draw; a feed from at least a portion of the C₆+C₇ rich bottoms stream; and a pyrolysis gasoline bottoms product stream.
 2. The system of claim 1 where the dimerizer is a thermal dimerizer.
 3. The system of claim 1 where a C₆-C₇ rich tar solvent makeup stream is drawn from the C₆-C₇ rich bottoms stream and the balance is directed to the dimerizer.
 4. A process for dimerizing cyclopentadiene (CPD), the process comprising: introducing a C₄-C₇ hydrocarbons stream to a debutanizer; debutanizing the C₄-C₇ hydrocarbons thereby producing: a C₄ overhead stream; a C₆+C₇ rich bottoms stream; and a C₅ rich side draw; introducing the C₅ rich side draw and at least a portion of the C₆+C₇ rich bottoms stream to a dimerizer; dimerizing the CPD in the dimerizer; and producing a bottoms product stream.
 5. The process of claim 4 where the dimerizing is thermal dimerizing.
 6. The process of claim 5 where the dimerizer is operated: at a temperature between about 200° F. (93° C.) and about 250° F. (121° C.); and at a pressure between about 35 psia (241 kPa) and about 60 psia (414 kPa).
 7. The process of claim 5 where the dimerizer is operated: at a temperature between about 210° F. (99° C.) and about 220° F.(104° C.); and at a pressure between about 40 psia (276 kPa) and about 50 psia (345 kPa).
 8. The process of claim 4 further comprising drawing a C₆-C₇ rich tar solvent makeup stream from the C₆+C₇ rich bottoms stream and directing the balance to the dimerizer.
 9. The process of claim 4 where the pyrolysis gasoline bottoms product stream comprises dicyclopentadiene (DCPD).
 10. The process of claim 9 further comprising making a product from the DCPD selected from the group consisting of an adhesion product, a resin, an ink, a paint, and combinations thereof.
 11. Dicyclopentadiene (DCPD) produced by the process of claim
 4. 12. A product produced from the DCPD of claim 11, where the product is selected from the group consisting of an adhesion product, a resin, an ink, a paint, and combinations thereof.
 13. An ethylene plant comprising: a system for dimerizing cyclopentadiene (CPD), the system comprising: a debutanizer comprising: a feed of C₄-C₇ hydrocarbons; a C₄ overhead stream; a C₆+C₇ rich bottoms stream; and a C₅ rich side draw; a dimerizer comprising: a feed from the C₅ rich side draw; a feed from at least a portion of the C_(6+C7) rich bottoms stream; and a pyrolysis gasoline bottoms product stream.
 14. The ethylene plant of claim 13 where the dimerizer is a thermal dimerizer.
 15. The ethylene plant of claim 13 where a C₆-C₇ rich tar solvent makeup stream is drawn from the C₆+C₇ rich bottoms stream and the balance is directed to the dimerizer. 